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Parallel tetramolecular quadruplexes may be formed with short oligodeoxynucleotides bearing a block of three or more guanines. We analyze the properties of sequence variants of parallel quadruplexes in which each guanine of the central block was systematically substituted with a different base. Twelve types of substitutions were assessed in more than different sequences.
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A functionalized verdazyl radical1was synthesized, which consists of a bodipy acceptor Aa phenyl-anthracene donor Dand a stable verdazyl radical R. The efficient intra-molecular energy transfer EnT from the anthracene moiety to the bodipy functional component was observed by time-resolved fluorescence spectroscopy and TRESR measurements. Such a unique DEP was not detected for either the parent verdazyl radical 2 without the bodipy acceptor or new compound 3 with an anthraquinone moiety instead of the bodipy component.
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More familiar these days in its film adaptation as "Dangerous Liaisons," Choderlos de Laclos' novel of tells of a wicked game of seduction, played for malicious sport by the Marquise de Mertreuil and the Vicomte de Valmont, in which Valmont violates both a virtuous wife and a young virgin fresh out of the convent. That is essentially the same story that Muller's intermissionless drama, written inrelates, but-with the cryptic notation that the play's "Timespace" is a "Drawing room before the French Revolu-tion. Air raid shelter after World War III"-he has the Marquise and Valmont act out all the roles of the drama in a graphic, bitter contest of love and death. In addition to playing themselves, the two principals play each other and Valmont's female conquests.
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